Substituent Effects in Heterogeneous Nitric Acid Oxidation of Alkylbenzenes
نویسندگان
چکیده
منابع مشابه
Atomistic oxidation mechanism of a carbon nanotube in nitric acid.
Motivated by recent experiments, we investigate how NO3-SWNT interactions become energetically favorable with varying oxidation state of a single-walled carbon nanotube (SWNT) using first-principles calculations. Chemisorption becomes less endothermic with respect to physisorption when the SWNT oxidation state is elevated. Importantly, the dissociative incorporation of an oxygen atom into the S...
متن کاملModifications in the nitric acid oxidation of D-glucose.
The nitric acid oxidation of D-glucose was reinvestigated in an effort to better understand and improve the oxidation and subsequent work up steps. The oxidation was carried out using a computer controlled reactor employing a closed reaction flask under an atmosphere of oxygen which allowed for a catalytic oxidation process with oxygen as the terminal oxidant. Removal of nitric acid from produc...
متن کاملEffects of Culture Conditions on Production of trans-Cinnamic Acid from Alkylbenzenes by Soil Microorganisms.
The production of trans-cinnamic acid from various alkylbenzenes by soil microorganisms was studied intensively by use of a co-oxidation technique. The microorganisms were grown on n-paraffins, and they did not use aromatic compounds as a carbon source when the preferred substrate was present in the medium. The effects of cell population, co-oxidation time, and type and mode of addition of the ...
متن کاملComparison study of the gas-phase oxidation of alkylbenzenes and alkylcyclohexanes
The goal of this paper is to present new experimental results obtained during the study of the gas phase oxidation of ethyl-benzene, n-hexyl-benzene, ethyl-cyclohexane and n-butyl-cyclohexane which belongs to two molecule families present in diesel fuels: alkylbenzenes and alkylcyclohexanes. Experiments were carried out in a jet-stirred reactor over the temperature range 550–1100 K. The new res...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1970
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.73.2_445